ASTM E299-2008 有机溶剂中过氧化物痕量的试验方法

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【英文标准名称】:StandardTestMethodforTraceAmountsofPeroxidesInOrganicSolvents
【原文标准名称】:有机溶剂中过氧化物痕量的试验方法
【标准号】:ASTME299-2008
【标准状态】:现行
【国别】:美国
【发布日期】:2008
【实施或试行日期】:
【发布单位】:美国材料与试验协会(US-ASTM)
【起草单位】:E15.01
【标准类型】:(TestMethod)
【标准水平】:()
【中文主题词】:
【英文主题词】:assay;organic;peroxides;spectrophotometric;Activeoxygen;Organicchemicals;Peroxides;Solvents--paints/relatedcoatings/materials;Spectrophotometry--absorption;Traceelements--chemicals
【摘要】:Dilutesolutionsofperoxidesinvariousorganicsolventsfrequentlyareusedascatalystsorreactioninitiators.Peroxidesalsocanbeformedthroughautoxidationincertainclassesofcompoundsincludingethers,acetals,dienes,andalkylaromatichydrocarbonsandpresentapotentialsafetyhazard.Thistestmethodprovidesaprocedurefordeterminingtheperoxideoractiveoxygenlevel.1.1Thistestmethod,coversorganicsolventscontainingactiveoxygenintherangefrom5to80x03BC;g/g(ppm)orhigher.Byusingaspecialreaction-absorptioncell,thetestmethodcanbeextendedtocovertherangefrom0to5ppm.Thetestmethodcanbeusedtodeterminenumerousperoxideclassesofvaryingreactivitysuchashydroperoxides,diacylperoxides,diaroylperoxides,peresters,andketoneperoxides.Thestabledi-tert-alkylperoxidesdonotreactundertheconditionsofanalysis.1.2Solventsthatcanbeanalyzedsuccessfullyincludesaturatedandaromatichydrocarbons,alcohols,ethers,ketones,andesters.Inaddition,thetestmethodisapplicabletoolefinicsolventsandtocertaincompoundsthatcontainx03B1;,x03B2;,andconjugatedunsaturation.Solidsamplesthataresolubleintheaceticacid-chloroformsolventalsocanbeanalyzed.1.3ThevaluesstatedinSIunitsaretoberegardedasstandard.Thevaluesgiveninparenthesesareforinformationonly.1.4Thisstandarddoesnotpurporttoaddressthesafetyconcerns,ifany,associatedwithitsuse.Itistheresponsibilityoftheuserofthisstandardtoestablishappropriatesafetyandhealthpracticesanddeterminetheapplicabilityofregulatorylimitationspriortouse.1.5ReviewthecurrentMaterialSafetyDataSheets(MSDS)fordetailedinformationconcerningtoxicity,firstaidpractices,andsafetyprecautions.
【中国标准分类号】:G63
【国际标准分类号】:71_100_99
【页数】:4P.;A4
【正文语种】:英语